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The phenolic compounds of pomegranate (Punica granatum L.) peel extracted by two methods (solvent and ultrasound-assisted) with five solvents (acetone, methanol, ethanol, water and ethyl acetate) were compared with supercritical fluid extraction (SFE). The total phenolic compounds were determined according to the Folin-Ciocalteu reagent using tannic acid as standard. The overall results showed that acetone with sonication produced the maximum amount of phenolic compounds from pomegranate peel extracts (PPE). Furthermore, the effect of the acetone extract of pomegranate peel (0.010-0.050 %) on the stability of soybean oil during heating at 60oC (oven test method) was determined by measuring peroxide and thiobarbitoric acid values. At a 0.050 % level of pomegranate peel extract, its antioxidant activity was greater than 0.02 % of the two synthetic antioxidants butylated hydroxyanisole (BHA) and butylated hydroxytoluene (BHT). The pomegranate peel extract possessed a relatively high antioxidant activity and might be considered as a rich source of natural antioxidant.

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Tea and sesame seed oils extracted by different methods (including supercritical fluid extraction (SFE), at a pressure of 350 atm, a temperature of 60oC, a static extraction time of 20 minutes, a dynamic extraction time of 30 minutes and 150 g kg-1 of ethanol as a modifier). Solvent (SE) and ultrasound-assisted solvent extraction (UE)), as natural anti-oxidants, were evaluated during 15 days storage by monitoring their effects on refined sunflower oil at 60oC. The peroxide value (PV) and the thiobarbituric acid (TBA) value were used to assess the antioxidant activity of these extracted oils. The highest extraction yields were from SE and SFE, while UE gave a lower yield. Considering oil extraction yield and antioxidant activity, SE and SFE were the preferred methods. The results showed that tea seed oil had strong antioxidant activity, which was almost equal to sesame oil. Therefore, tea seed oil can be used in the same way as sesame seed oil in fat, oil and other food products as a natural antioxidant to suppress lipid oxidation.

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Changes in the fatty acid content, during frozen storage at -24°C of Caspian kutum (Rutilus frisii kutum), golden grey mullet (Liza aurata), common carp (Caprinus carpio), pike perch (Sander lucioperca) and common kilka (Clupeonella cultiventris caspia), caught from south Caspian Sea were studied in the present work. Changes in saturated fatty acids (SFAs), monounsaturated fatty acids (MUFAs), polyunsaturated fatty acids (PUFAs), ecosapentaenoic acid plus docosahexaenoic acid/palmitic acid (EPA+DHA/C16), n3 PUFA/n6 PUFA (n3/n6) and polyunsaturated fatty acids/saturated fatty acids (PUFA/SFA) were investigated during a six month period. Results indicated that due to the decrease in unsaturated fatty acids particularly PUFAs (9.25-23.03%), and lower ratios of n3/n6 (2.02-6.06), EPA+DHA/C16 (polyene index; 0.21-0.65) and PUFA/SFA (0.18-0.64) the poststorage nutritional values of these species significantly decrease.

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Phenolic compounds, especially those of plant origin, constitute an essential part of the human diet, and are of considerable interest due to their antioxidant properties. In this study, Ultrasound-Assisted Extraction (UAE), Microwave-Assisted Extraction (MAE), as well as Maceration Extraction (ME) methods were applied for phenolic compounds’ extraction from pistachio green hull. Response surface methodology was employed to optimize the extraction conditions as regards the yield of the compounds. A Central Composite Design (CCD) was employed to investigate the effects of three independent variables, namely liquid-to-solid ratio (8-20 times), temperature (25-65 °C) and time (5-45 minutes) on the dependent variable (level of total phenolic compounds). The results indicated that within the same extraction time, the extraction yield through UAE was higher than those in ME and MAE methods. Correlation coefficients (R2) of the models for UAE, MAE and ME methods were 0.95, 0.96 and 0.94, respectively. The optimal conditions for extraction of phenolic compounds from pistachio green hull through ME, UAE, and MAE methods were 20(v/w), 65°C, 45 minutes; 20(v/w), 65°C, 25 minutes; and 20(v/w), 65°C, 45 minutes, respectively. Under optimized conditions the experimental values well agreed with the values predicted by the proposed models.

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The present study explores the chemical constitution and antioxidant activity of the essential oils of the aerial parts of Artemisia dracunculus L. and the flower heads of Matricaria chamomilla L. GC-MS analysis revealed the presence of (Z)-anethole (51.72%), (Z)-β-ocimene (8.32%), methyleugenol (8.06%), limonene (4.94%) and linalool (4.41%) in Artemisia dracunculus and (E)-β-farnesene (24.19%), guaiazulene (10.57%), α-bisabolol oxide A (10.21%), α-farnesene (8.7%) and α-bisabolol (7.27%) in M. chamomilla L.. The antioxidant activity (AOA) of the essential oils was investigated using DPPH• (2, 2′-diphenyl 1-picrylhydrazyl) free radical scavenging and β-carotene/linoleic acid methods. The essential oil EC50 values were determined as 3.19±0.13 and 5.63±0.20 mg ml-1 for A. dracunculus and M. chamomilla, respectively. Further, the A. dracunculus L. essential oil (ADEO) and M. chamomilla L. essential oil (MCEO) were able to reduce the oxidation rate of soybean oil under accelerated conditions at 60 °C (oven test).

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Changes in the fatty acid composition and biochemical indices of mackerel (which has a substantial lipid content) and shark (which has negligible lipid content) fillets stored at - 18°C for up to six months were measured. Lipid content was measured (6.35% and 1.38%) in mackerel and shark, respectively; however it decreased during frozen storage in both fish species. In analysis of fatty acids the amount of PUFA, especially
-3 ones, was more predominant in mackerel than shark, nevertheless, fatty acid composition has changed in both species during frozen storage. The amount of saturated fatty acids in contrast with unsaturated fatty acids increased due to oxidation of PUFA. The decrease in PUFA compounds (40.1% and 23.94%) was as follows:
-3 (48% and 42.83%),
-3/
-6 ratio (41.36% and 50%), PUFA/SFA ratio (56% and 42.23%) and EPA+DHA/C16 ratio (55.55% and 46.66%) in mackerel and shark, respectively. For both species, tiobarbituric acid (TBA), peroxide (PV), free fatty acids (FFA) and total volatile base nitrogen (TVB-N) values were significantly (P< 0.05) increased with storage time. The results showed that, among these indices, changes in the PV and TBA in mackerel were significantly (P< 0.05) larger than in shark; but changes of FFA and TVB-N in shark were significantly (P< 0.05) higher than in mackerel. It means that oxidative and hydrolytic deterioration are promoter factors of biochemical changes in mackerel and shark, respectively.

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Virgin olive oil due to having unsaturated fatty acids is exposed to various types of corruptions such as enzymatic reactions and lipid oxidation. One way to prevent oxidation of oils and fats is addition of antioxidants. Rosemary due to phenolic compounds and other antioxidant compounds have antioxidant as well. In this study, the extraction phenolic compounds of rosemary leaves in virgin olive oil with was performed using by ultrasonic technique. In this method, rosemary leaves with three levels (5, 7 and 10%) and three ultrasonic times (10, 15 and 20 minutes) were added to the olive oil. Phenolic compounds present in the extracts, was measured. The results showed that in the ultrasonic method the sample of virgin olive oil with 10% rosemary and 10 minute extraction time has the highest total polyphenols (457.59 ppm). In this case study the effect of this extract in retarding oxidation of virgin olive oil during the 4-month by determining the peroxide value, thiobarbituric acid, oxidative stability, at the end of each month were reviewed. After four months keeping, the ultrasonic's peroxide number, the thiobarbituric acid (20.75meq O₂/kg oil, 1.32 molonaldehyde/kg oil, respectively) significantly decreased. The results of antioxidant activity of the extracts using rancimat method showed that during the period of induction at 110 °C  in the ultrasonic's sample (29.10 hours) with respect to control's sample (6.28 hours) are increased. The acidity value of the ultrasonic's sample (2.05 FFA %) and thermal's sample (1.84 FFA %) are less than the control's (3.18 FFA %). Measurement results showed that the amount of chlorophyll pigments within ultrasonic's sample (1.4mg/kg) had the highest value and with respect to control's sample (0.63mg/kg) had high value. Also in the sensory evaluation, the ultrasonic's sample has top rated in terms of taste, odor, bitter and won general acceptance. Therefore, the phenolic compounds in the olive oil containing rosemary and extracted by ultrasonic method, be able to retard the oxidation process well. Thus, rosemary can be recommended as a source of natural antioxidants for increase virgin olive oil oxidative stability.  

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The drying behavior and characteristics of date paste were studied at temperatures of 60, 70, and 80ºC as thin layer with sample thicknesses of 1, 1.5, and 2 cm in a laboratory scale vacuum chamber. Modeling of drying kinetics of date paste was investigated based on the specific temperatures and sample thicknesses. The experimental moisture loss data were fitted to eight thin layer drying models available in the literature. The modified Henderson-Pabis, Verma, and Jena-Das models showed better fitness to the experimental drying data compared to the other models. The effective moisture diffusivity ranged between 6.0854×10-8 and 4.868×10-7 m2 s-1. Effective diffusivity increased with the increase in temperature and sample thickness. The temperature dependence of effective moisture diffusivity was expressed by an Arrhenius type equation.

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This study investigated the fatty acids profile, oxidative stability indices, and bioactive compounds of virgin and processed olive oils (Leccino and Frantoio cultivars). Results showed that fatty acid profile of the studied oils contained mostly oleic acid followed by palmitic and linoleic acid. Acid values of virgin Frantoio and processed Leccino were 0.78 and 0.18 mg KOH/g oil, with peroxide values (PV) of 8.74 and 6.03 meq O₂/kg oil, respectively. Virgin Leccino had the highest oxidative stability index with induction period of 18.83 h. The highest contents of phenolics, 321.14 mg/kg, tocopherols, 455.25 mg/kg, and sterols, 2189.1 mg/kg, were recorded in virgin Leccino oil. Laboratory processing of virgin olive oil decreased the phenolics to 70%, tocopherols to 50%, and sterols to 25%. Finally, based on the higher content of antioxidant compounds, the virgin Leccino oil had higher oxidative stability and bioactivity than Frantoio oil.

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Olive cultivars Bladi and Arbequina were collected and their oil was extracted (cold press). Oil was refined under bleaching and deodorization conditions for 30 minutes at 55-50°C and their property was compared with the virgin olive oil. Virgin and refined oils of the cultivars were processed by fryer heating at 180°C (intervals of 0, 1, 2, 4, and 8 hours) and indexes of fatty acid, free fatty acid, peroxide, thiobarbituric acid, polar compounds, conjugated dienes and trienes, Rancimat, color, total polyphenol, tocopherol, chlorophyll and carotenoid were compared. Results showed that these oils mainly contained oleic (48.69-60.18%), palmitic (18.31-27.02%), linoleic (7.54-18.58%), palmitoleic (3.9-3.08%), stearic (1.78-2.53%), and linoleic acids (1.87-0.22%). According to the results, it was recommended to refine virgin olive oil by mild bleaching and deodorization to save bioactive compounds. Due to the heating condition, the relative amounts of unsaturated fatty acids (22.37-50.6%), polyphenols, tocopherols, chlorophyll, carotenoid and oxidative stability decreased and the relative amounts of saturated fatty acids (14.2-17.1%), acidity, peroxide, conjugated dienes and trienes, polar compounds, and thiobarbituric acid increased significantly, but the colorant initially decreased and then increased (P< 0.05). Due to polar compounds, for frying process, mild refined oil was better than extra virgin oil.

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The use of essential oils as the preservative agents in food industry faces the problem of interactions with food matrix components, low solubility in aqueous phase, high volatile character and sensitivity to environmental conditions. The aim of this study was to enhance thermal stability and antioxidant activity of Thyme essential Oil (TO) by encapsulation in Chitosan Nanoparticles (CS-NP). TO was encapsulated in CS-NP with an emulsion–ionic gelation crosslinking method and the construction was confirmed by Fourier Transform Infrared spectroscopy (FT-IR) and thermogravimetric analysis techniques. The effect of CS: TO weight ratio encapsulation efficiency, loading capacity, particle size and zeta potential of TO-loaded Chitosan Nanoparticle (CS-NP-TO) were investigated. The encapsulated TO was decomposed at a higher temperature (318-325.4ºC) than free TO (170ºC) reflecting the enhanced thermal stability of TO by encapsulation. Also, when TO was encapsulated in CS-NP, antioxidant activity proved to be superior from that of free TO. The considerable antioxidant activity and thermal stability reveal that such particles have promising application for delivery of TO in medicine, food and feed.

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The aim of this study was to optimize the encapsulation conditions of Garlic Oil (GO) with β-cyclodextrin (GO/β-CD) inclusion complex by the co-precipitation method. Response surface optimization of encapsulation of GO with β–CD was performed with a three-variable, three-level and the optimum conditions were as follows: temperature: 35^oC, Core/Wall: 8/100, and Wall/Solvent: 5.5/100. The complex was characterized by different techniques including UV–visible spectroscopy, Fourier transform infrared spectroscopy, X-ray diffractometry, and differential scanning calorimetry. Spectroscopic techniques and morphological analysis by Scanning Electron Microscope (SEM) confirmed formation of GO/β-CD. The in vitro release profile of GO from the GO/β-CD complex at different pH values (1.5, 4, 5.5, and 6.5) at 37^oC showed that the maximum and minimum release of GO after two days were 36.59% at pH 6.5, and 1.12% at pH 4, respectively. In simulation of gastrointestinal tract, the maximum and minimum release of GO were in colon (10.29%), and stomach (0.60%), respectively. Therefore, GO/β-CD complex could be suggested in formulation of food systems such as salad dressing and sausage.

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The bioactive compounds of barberry such as water-soluble vitamins are used in medical and food industries. In this study, the effect of different extraction conditions and various process conditions were studied on water-soluble vitamins profile. The extraction conditions included varieties (species) are of fruits (B. integerrima: A, B. vulgaris: P), solvents (Water: W, Ethanol: E), light (Presence: L, Absence: T), pH (3 and 1.5), and temperature (25 and 50ºC). The process conditions included heating (95 and 80°C), chilling (ref 1, 2 months), freezing (con), microwave (mic) and gamma irradiation (γ at doses of 0.5, 1, 2.5, 5, 7.5, 10 kGy). The highest and lowest amounts of water-soluble vitamins in various extracts of different extraction conditions were respectively as follows: vitamin C in AWL1.550 (highest) and PEL350 (lowest); B₅ in PWL1.550 and AEL1.525, AWL1.550; B₆ in AWT350, and AEL1.550; B₁ in PET350 and PET1.550; folic acid in AET350 and PWT350; biotin in AEL350 and AEL1.550; B₂ in AET350 and PWL350 extracts. The highest and lowest amounts of water-soluble vitamins in various process conditions were respectively as follows: vitamin C (A_con 460 (highest), A_ref1 146.87 (lowest), P_con 242.96 (highest), P_mic 21.52 (lowest)), B₅ (A_γ0.5 2919.18, A₉₅ 1312.42, P_γ10 3110.88, P_ref2 1051.52), B₆ (A_con 36.30, A_γ7.5 21.04, P_γ10 12.70, P₉₅ 8.73), B₁ (A_con 2113.00, A_ref2 965.09, P_con 2298.15, P_γ10 217.76), folic acid (A_γ0.5 1700.38, A_γ10 947.11, P_con 104.78, P_γ10 in B. vulgaris after processing was not found), biotin (A_mic 2267.58, A_γ10 1404.63, P_con 324.72, P_γ2.5 118.33), and B₂ (A_γ0.5 586.43, A_γ10 274.34, P_con 297.19, P_γ10 6.79).
 

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Advanced glycation end products (AGEs) are a group of compounds formed during the Maillard reaction, which can have adverse effects. This study aims to investigate the formation of fluorescent AGEs using the response surface method (RSM). Factors such as protein type ((whey protein 2.0, 3.5, and 5.0 %w/v) and casein (1.0, 2.0, and 3.0 %w/v)), three types sugar ((glucose and frouctose (0.2, 0.6, and 1.0 M) and lactose (0.1, 0.3, and 0.5 M)), and pomegranate peel (PPE) concentration (250.0, 500.0, and 750.0 ppm) along with their interactions are analyzed. The results of this study showed that, the type of protein, type of sugar, and concentration of phenolic extract from pomegranate peel were effective in preventing the formation of AGEs, and the pomegranate peel extract (specially at 750.0 ppm) was able to effectively prevent glycation reaction. According to the results, protein type and concentration significantly influence AGEs formation. The inhibitory activity of the extract in the model system containing casein was lower than the system containing whey protein, and overall, the inhibitory power decreased with an increase in protein concentration. By changing the type of sugar present in the model system, the inhibitory behavior of the pomegranate peel extract became complex, showing increased, decreased, or no effect in some cases. Further investigations can suggest the use of this extract, especially in the formulation of food products, including infant formulas.
 

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In this study, the combined effects of various experimental parameters (solvent concentration, extraction temperature, pH, extraction time, and light conditions) on the recovery of phytochemical compounds from the jujube (Ziziphus jujuba var vulgaris) fruit were investigated in a batch system using a 2⁵ full-factorial design. The independent variables were coded at two levels and their actual values were selected based on the results of single-factor experiments. Total Phenolic Content (TPC), Total Monomeric Anthocyanin Content (TMAC), and vitamin C content values were used for the determination of phytochemical compound content in jujube extract. The results showed that pH, extraction temperature, and solvent concentration were the most significant (P< 0.05) factors affecting the TPC, TMAC, and vitamin C content. The optimal extraction conditions of phytochemical compounds were found to be as follows: ethanol concentration of 60%, pH of 3, extraction time of 180 min, extraction temperature of 25°C, and absence of light. In the optimized conditions, the maximum experimental values for TPC, TMAC, and vitamin C content were 164.51 mg gallic-acid equivalents per gram of dry weight (mg GAE g^-1 DW), 52.94 mg cy-3-glu 100 g^-1 DW, and 137.12 mg L-AA 100 g^-1 DW, respectively. The high content of phytochemical compounds in the jujube extract indicates that jujube extract might be considered as a potential source of nutraceuticals in the future.